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Ms Mc Carthy first met Mr Hopkins when she was in her late 20s and they were both involved in Labour politics in her home town of Luton.
In 1994, when she was chairwoman of Luton North constituency Labour Party (CLP) and he chaired Luton South CLP, they went out for lunch, with Ms Mc Carthy believing it was solely to discuss political issues.
The former shadow environment secretary is the first MP to make specific claims of inappropriate behaviour since the Westminster scandal erupted.
Elected at the same time as Tony Blair became Prime Minister in 1997, Kelvin Hopkins has enjoyed a long career in parliament spanning two decades as the representative for Luton North.
Kelvin Hopkins, pictured with his wife Pat after winning his seat of Luton North at the election.
He has been suspended from the Labour Party pending an investigation into alleged sex abuse and harassment He also sent a postcard, which appears to be dated 1996, in an envelope to her place of work, asking whether her employer specialised in 'pretty, petite brunettes'.
The notes allegedly began in 1994 when she was a young Labour activist and went out for lunch with Mr Hopkins believing they would solely talk politics.
This is the latest news to rock Westminster after a series of allegations made against standing MPs have prompted a number of resignations in recent weeks.
Mr Hopkins 'categorically denies' any inappropriate conduct in relation to Ms Etemadzadeh.
A note sent in the run-up to the 1997 General Election said: 'You know I think you are lovely ... She first met Mr Hopkins as a young activist having grown up in his constituency of Luton.
After qualifying as a solicitor in 1994, Ms Mc Carthy worked as a lawyer for Merrill Lynch Europe and then the Labour Party.
Now Corbyn's party is facing further turmoil as Kelvin Hopkins faces fresh allegations.
The 76-year-old has already been suspended after activist Ava Etemadzadeh, 27, complained to Jeremy Corbyn's office claiming the veteran married MP rubbed his crotch against her.
The Bristol East MP said she found his behaviour 'upsetting' but did not feel she had anywhere to turn to about it.