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Since the flood was accompanied by much volcanism (see Noah's Flood…, How did animals get from the Ark to isolated places? ), fossils formed in the early post-flood period would give radiocarbon ages older than they really are.
In summary, the carbon-14 method, when corrected for the effects of the flood, can give useful results, but needs to be applied carefully.
These techniques are applied to igneous rocks, and are normally seen as giving the time since solidification.
The isotope concentrations can be measured very accurately, but isotope concentrations are not dates.
It makes no sense at all if man appeared at the end of billions of years.
So, we have a “clock” which starts ticking the moment something dies.
Obviously, this works only for things which were once living.
That is, they take up less than would be expected and so they test older than they really are.
Furthermore, different types of plants discriminate differently.When a “date” differs from that expected, researchers readily invent excuses for rejecting the result.